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Saltpeter



         



</table> The chemical compoundpotassium nitrate is a naturally occurring mineral source of nitrogen. It is a nitrate with chemical formula KNO3. Its common names include saltpetre (from Medieval Latin sal petrae: "stone salt" or possibly "salt of Petra"), American English saltpeter, Chilean saltpetre, and nitre. The name saltpeter is also applied to sodium nitrate. It is the oxidising (oxygen-supplying) component of gunpowder. Prior to the large-scale industrial fixation of nitrogen (the Haber process), a major source of Potassium nitrate was the deposits crystallising from cave walls or the drainings of decomposing organic material. Dung-heaps were a particularly common source: ammonia from the decomposition of urea and other nitrogenous materials would undergo bacterial oxidation to produce nitrate. One of the most useful applications of potassium nitrate is in the production of of nitric acid, by adding concentrated sulfuric acid to an aqueous solution of potassium nitrate, yielding nitric acid and potassium sulfate which are separated through fractional distillation. Potassium nitrate is also used as a fertiliser, as a model rocket propellant, and for certain pyrotechnic combinations, such as the renowned sugar-Potassium nitrate mix which gives rise to a lot of smoke. In the process of food preservation, potassium nitrate is a common ingredient of salted meat. In England, the privilege of manufacturing explosives had been in the hands of the family of John Evelyn, the celebrated diarist, as a crown monopoly since before 1588. An urban legend holds that soldiers, sailors, and other young men in institutional situations are secretly administered Potassium nitrate in their food, especially during bootcamp, to suppress their sexual urges. It is conjectured that the troops were employing a folk etymology and replacing "salt" with "soft". The reduction in sexual urges does in fact occur, but is caused by physical exhaustion related to intense training.
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Properties

General

Name Potassium nitrate
Chemical formula KNO3
Appearance White or dirty gray solid

Physical

Formula weight 101.1 amu
Melting point 607 K (334 °C)
Boiling point decomposes at 673 K (400 °C)
Density 2.1 ×103 kg/m3
Crystal structure Aragonite
Solubility 38 g in 100g water

Thermochemistry

ΔfH0gas ? kJ/mol
ΔfH0liquid -483 kJ/mol
ΔfH0solid -495 kJ/mol
S0gas, 1 bar ? J/mol·K
S0liquid, 1 bar ? J/mol·K
S0solid ? J/mol·K

Safety

Ingestion May cause GI irritation, nausea, vomiting, diarrhea.
Inhalation Irritation, long term exposure may be fatal.
Skin Low hazard.
Eyes Low hazard.

SI units were used where possible. Unless otherwise stated, standard conditions were used.

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