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A quantum phase transition (QPT) is a phase transition between different quantum phases (phases of matter at zero temperature). Contrary to classical phase transitions, the quantum phase transitons can be only be accessed by varying a physical parameter - such as magnetic field or pressure - at absolute zero temperature. The transition describes an abrupt change in the ground state of a manybody system due to its quantum fluctuations. Such quantum phase transitions can be first-order or continuous.
To understand quantum phase transitions, it is useful to contrast them to classical phase transitions (CPT) (also called thermal phase transitions). A CPT describes a discontinuity in the thermodynamic properties of a system. It signals a reorganization of the particles; A canonical example is the freezing transition of water describing the transition between liquid and ice. The classical phase transitions are driven by a competition between the energy of a system and the entropy of its thermal fluctuations. A classical system does not have entropy at zero temperature and therefore no phase transition can occur.
In contrast, even at zero temperature a quantum-mechanical system has quantum fluctuations dictated by Heisenberg?s famous uncertainty principle and therefore can still support phase transitions. As a varying physical parameter is swept, the quantum fluctuations can drive a phase transition into a different phase of matter. A canonical quantum phase transition is the well-studied superconductor/insulator transition in disordered thin films which separates two quantum phases having different symmetries. Quantum magnets provide another example of QPT.