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Nitrogen dioxide



         


</table> </table> The chemical compoundnitrogen dioxide is an orange/brown gas with a characteristic sharp, biting odor. It is considered an insidious deadly poison by inhalation. Nitric oxide (NO) spontaneously produces the dioxide when exposed to air:
2 NO + O2 → 2NO2
It is also generated by various nitric acid reactions, e.g. when metals, such as copper or silver, are exposed to nitric acid. It reacts readily with water, even at normal temperature and pressure, where it disproportionates to nitric and nitrous acid. That reaction is used in the Ostwald process. Vapor pressure, mmHg: 400 at 80°C
Vapor density (air=1): 1.58
Specific gravity/density: 1.4494 at 20°C
Solubility in water: Reacts
Odor threshold: 2.0 mg/m³
Heat of vaporization: 9.110 kcal/mole




Properties

General

Name Nitrogen dioxide
Chemical formula NO2
Appearance brown/orange gas

Physical

Formula weight 46.01 amu
Melting point -263.85 K (9.3 °C)
Boiling point -252.00 K (21.15 °C)
Density  
Crystal structure  
Solubility  

Thermochemistry

ΔfH0gas   kJ/mol
ΔfH0liquid   kJ/mol
ΔfH0solid   kJ/mol
S0gas, 1 bar   J/mol·K
S0liquid, 1 bar   J/mol·K
S0solid   J/mol·K

Safety

Ingestion  
Inhalation Deadly poison! Insidious. Can cause lung edema or death after several days delay. 100 ppm dangerous, 200 ppm may be lethal for short exposures.
Skin  
Eyes  
More info

SI units were used where possible. Unless otherwise stated, standard conditions were used.

Disclaimer and references </font>

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