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Information architecture is the art and science of structuring knowledge (technically data), and defining user interactions (also see use case).
In the context of Web design, information architecture is the organization of information to aid in information retrieval. A common example of this is the categorization of similar information into sections of a website, with those sections displayed in pages. Information Architects create a variety of project deliverables including Site Architecture Maps and Wireframes (also known as Page Schematics).
An Information Architecture Design Document template might look something like this:
Information Architecture may well be viewed as an umbrella phrase, given its close resemblance to Information Technology, and all the catch-phrases IT conjures up.