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Electrode is a Pokemon character. Electrode evolves from Voltorb. It explodes if anything annoys or disturbs it. This is called "Self-Destruct", its favorite attack.
In Super Smash Bros Melee, Electrode comes out of a Pokéball, when it does, it powers up for a few seconds, before exploding, damaging even the person that originaly threw the pokéball, also, just when Electrode turns black (just before exploding) it can be picked up and thrown, like a bob-bomb (although the chance of it exploding while you're still holding it is high)
Electrode also appears in Smash Bros, where it is one of the Pokémon that randomley pop out of the door of the silph co. building in the Saffron City level. It, of course, blows up soon after appearing