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Unlike many of the other countries in the region, Chile has a long history of democratic Presidents. The President of Chile is both the chief of state and the head of government.
| Name | Took Office | Left Office | Party |
|---|---|---|---|
| Manuel Blanco Encalada | 1826 | 1826 | |
| Agustín Eyzaguirre | 1826 | 1827 | acting |
| Ramón Freire y Serrano | 1827 | 1827 | |
| Francisco Antonio Pinto Díaz | 1827 | 1829 | |
| Francisco Ramón Vicuña Larraín | 1829 | 1829 | temporary |
| Francisco Ruiz Tagle | 1830 | 1830 | temporary |
| Francisco Errázuriz | 1831 | 1831 | temporary |
| José Tomás Ovalle | 1830 | 1830 | interim |
| José Joaquín Prieto Vial | 1830 | 1841 | |
| Manuel Bulnes Prieto | 1841 | 1851 | |
| Manuel Montt Torres | 1851 | 1861 | |
| José Joaquín Pérez Mascayano | 1861 | 1871 | |
| Federico Errázuriz Zañartu | 1871 | 1876 | |
| Aníbal Pinto Garmendia | 1876 | 1881 | |
| Domingo Santa María González | 1881 | 1886 | |
| José Manuel Balmaceda | 1886 | 1891 | |
| Jorge Montt Álvarez | 1891 | 1896 | |
| Federico Errázuriz Echaurren | 1896 | 1901 | |
| Germán Riesco Errázuriz | 1901 | 1906 | |
| Pedro Montt Montt | 1906 | 1910 | |
| Elías Fernández Albano | 1910 | 1910 | temporary |
| Emiliano Figueroa | 1910 | 1910 | temporary |
| Ramón Barros Luco | 1910 | 1915 | |
| Juan Luis Sanfuentes Andonaegui | 1915 | 1920 | |
| Arturo Alessandri Palma | 1920 | 1925 | |
| Luis Altamirano | 1924 | 1925 | temporary |
| Luis Barros Borgoño | 1925 | 1925 | temporary |
| Emiliano Bello C. | 1925 | 1925 | temporary |
| Emiliano Figueroa Larraín | 1925 | 1927 | |
| Carlos Ibáñez del Campo | 1927 | 1931 | |
| Juan Esteban Montero Rodríguez | 1931 | 1932 | |
| Carlos Dávila | 1932 | 1932 | |
| Guillermo Blanche | 1932 | 1932 | |
| Abraham Oyanedel | 1932 | 1932 | |
| Arturo Alessandri Palma | 1932 | 1938 | |
| Pedro Aguirre Cerda | 1938 | 1941 | |
| Juan Antonio Ríos Morales | 1942 | 1946 | |
| Gabriel González Videla | 1946 | 1952 | |
| Carlos Ibáñez del Campo | 1952 | 1958 | |
| Jorge Alessandri Rodríguez | 1958 | 1964 | |
| Eduardo Frei Montalva | 1964 | 1970 | PDC |
| Salvador Allende Gossens | 1970 | 1973 | UP (PS) |
| Augusto Pinochet Ugarte | 1973 | 1990 | military regime |
| Patricio Aylwin Azócar | 1990 | 1994 | CPD (PDC) |
| Eduardo Frei Ruiz-Tagle | 1994 | 2000 | CPD (PDC) |
| Ricardo Lagos Escobar | 2000 | 2006 | CPD (PS/PPD) |